Priority substances in Adriatic Sea. Case study: Water of Durrеs and Vlora ports, Albanian coastline
Bledar Murtaj

, Esmeralda Halo

, Aurel Nuro

, Jonida Tahiraj, Sonila Kane, Elda Marku, Pranvera Lazo
Abstract: The elevated activities in the port areas are the main reasons for water pollution by priority substances, which are of growing concern due to their potential toxicity to aquatic organisms and human health. Therefore, this paper reports the concentrations of organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), and BTEX (benzene, toluene, ethyl benzene, and o-, m-, and p-xylenes), analyzed in water samples from two main ports, Durrеs and Vlora. To assess the pollution status of these areas 24 water samples in total were collected, of which 12 in the port of Durrеs and 12 in Vlora port, in June 2022. Analyses of this compounds were performed using a gas chromatograph (Varian 450 GC) equipped with ECD and FID detectors. BTEX were analyzed using the HS/SPME technique, followed by the GC/FID technique for their qualification and quantification. Organochlorine pesticides and their degradation products were detected in all water samples. Their presence may be related to their previous uses. PCBs, PAHs, and BTEX were found in almost all analyzed samples. The higher levels were found in stations inside port areas. Their presence is due to anthropogenic factors (intense activity and ship transport) in these areas. The reported levels of these priority substances in water samples from Durrеs and Vlora's ports were higher and comparable with reported levels of them from other stations in the Adriatic Sea. Although the production and use of these substances have been banned for decades, their presence continues to be reported.
Keywords: BTEX; Durrеs and Vlora ports; GC/ECD/FID; OCPs; PAH; PCBs
Citation: Murtaj, B., Halo, E., Nuro, A., Tahiraj, J., Kane, S., Marku, E. & Lazo, P. (2026). Priority substances in Adriatic Sea. Case study: Water of Durrеs and Vlora ports, Albanian coastline. Bulg. J. Agric. Sci., 32(3), 741–749
| References: (click to open/close) | Akkanen, J., Tuikka, A. & Kukkonen, J. V. K. (2005) Comparative sorption and desorption of benzo[a]pyrene and 3, 4, 3′, 4′-tetrachlorobiphenyl in natural lake water containing dissolved organic matter. Environ. Sci. Technol., 39(19), 7529 - 7534. Chen, M. Y., Yu, M., Luo, X. J., Chen, S. J. & Mai, B. X. (2010) The factors controlling the partitioning of polybrominated diphenyl ethers and polychlorinated biphenyls in the water-column of the Pearl River Estuary in South China. Mar. Pollut. Bull., 62, 29 - 35. https ://doi.org/10.1016/j.marpolbul.2010.09.018. Corsi, I., Tabaku, A., Nuro, A., Beqiraj, S., Marku, E., Perra, G., Tafaj, L., Baroni, D., Bocari, D., Guerranti, C., Cullaj, A., Mariottini, M., Shundi, L., Volpi, V., Zucchi, S., Pastore, A. M., Iacocca, A., Trisciani, A., Graziosi, M., Piccinetti, M., Benincasa, T. & Focardi, S. (2010). “Ecotoxicologial assessment of Vlora Bay (Albania) by a biomonitoring study using an integrated approach of sub-lethal toxicological effects and contaminants levels in bioindicator species”. Journal of Coastal Research, Special Issue 58 - Coastal Research in Albania: Vlora Gulf [Tursi & Corselli], 116 - 120. DOI:10.2112/SI_58_1. Directive 2008/105/EC of The European Parliament and of The Council on environmental quality standards in the field of water policy, amending and subsequently repealing Council Directives 82/176/EEC, 83/513/EEC, 84/156/EEC, 84/491/EEC, 86/280/EEC and amending Directive 2000/60/EC of the European Parliament and of the Council. EC (2000). Directive 2000/60/EC of the European Parliament and of the Council establishing a framework for Community action in the field of water policy. OJ L327, 22.12.2000. ISO 5667-3:2018. Water quality - Sampling - Part 3: Preservation and handling of water samples. Lekkas, Th., Kolokythas, G., Nikolaou, A., Kostopoulou, M., Kotrikla, A., Gatidou, G., Thomaidis, N. S., Golfinopoulos, S. & Makri, C. (2004) Evaluation of the pollution of the surface waters of Greece from the priority compounds of List II, 76/464/EEC Directive, and other toxic compounds. Environment International, 30(8), 995 – 1007. Li, J., Zhang, G., Qi, S., Li, X. & Peng, X. (2006). Concentrations, enantiomeric compositions, and sources of HCH, DDT and chlordane in soils from the Pearl River Delta, South China. Sci. Total Environ., 372, 215 - 224. Magi E., Bianco R., Ianni C. & Di Carro M. (2002) Distribution of polycyclic aromatic hydrocarbons in the sediments of the Adriatic Sea. Environmental pollution, 119, 91 – 98. Mandić, J. & Vrančić, M. P. (2017) Concentrations and origin of polycyclic aromatic hydrocarbons in sediments of the middle Adriatic Sea. Acta Adriatica: International Journal of Marine Sciences, 58(1), 3 – 24. Marini, M. & Frapiccini, E. (2013) Persistence of polycyclic aromatic hydrocarbons in sediments in the deeper area of the Northern Adriatic Sea (Mediterranean Sea). Chemosphere, 90(6), 1839 - 1846. Murtaj, B., Nuro, A., Como, E., Marku, E. & Mele, A. (2013) “Study of Organochlorinated Pollutants in Water Samples of Karavasta Lagoon”. Science Bulletin of Faculty of Natural Sciences, Nr 14, 178 - 185. Tirane, Albania. Nuro, A., Marku, E., Murtaj, B. & Mance, S. (2014) “Study of Organochlorinated Pesticides, their Residues and PCB Concentrations in Sediment Samples of Patoku Lagoon”. International Journal of Ecosystems and Ecology Sciences (IJEES), 2(1), 15 - 20. Stogiannidis, E. & Laane, R. (2015) Source characterization of polycyclic aromatic hydrocarbons by using their molecular indices: an overview of possibilities. Rev. Environ. Contam. Toxicol., 234, 49 - 133. Wang, B., Yu, G., Yu, Y. J., Huang, J., Hu, H. Y. & Wang, L. S., (2009) Health risk assessment of organic pollutants in Jiangsu Reach of the Huaihe River, China. Water Sci. Technol., 59(5), 907 - 916. Yang, J., Qadeer, A., Liu, M., Zhu, J., Huang, Y., Du, W. & Wei, X. (2019). Occurrence, source, and partition of PAHs, PCBs, and OCPs in the multiphase system of an urban lake, Shanghai. Appl. Geochem., 106, 17 - 25.
|
|
| Date published: 2026-06-25
Download full text